From the British show The Avengers Emma Peel (Diana Rigg) and John Steed (Patrick Macnee) popularized the genre of spy-fi. With elements of undercover spy missions and science fiction, the series was extremely successful.
Diana Rigg , Although she was Emma Peel on the Avengers, She was a James Bond Woman. The only woman James Bond ever married, only to loose her to the mean and evil Blofeld. Movie was "On Her Majesty's Secret Service"