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A serene movie goddess and burgeoning director who's the sweetheart of a beloved Hollywood hunk? That would be Angelina Jolie. Her story is at Biography.com.

A serene movie goddess and burgeoning director who's the sweetheart of a beloved Hollywood hunk? That would be Angelina Jolie. Her story is at Biography.com.

Brad Pitt cheated on Jennifer Aniston with Angelina Jolie on the set of Mr. and Mrs. Smith

Brad Pitt cheated on Jennifer Aniston with Angelina Jolie on the set of Mr. and Mrs. Smith

Rumors swirled that Angelina Jolie and Brad Pitt were being flirtatious and that a romance was brewing when they were shooting "Mr. and Mrs. Smith" in 2004. But Brad -- who was married to Jennifer Aniston at the time -- and Angie both denied it. (Yeah, right!)

Angelina Jolie's life in pictures

Rumors swirled that Angelina Jolie and Brad Pitt were being flirtatious and that a romance was brewing when they were shooting "Mr. and Mrs. Smith" in 2004. But Brad -- who was married to Jennifer Aniston at the time -- and Angie both denied it. (Yeah, right!)

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