photojojo: “Here’s a gorgeous blend of photography and painting. Timothy Pakron selectively exposes images of people’s faces by painting developer onto paper in a darkroom. Painting a Portrait with Photo Developer ”
This infographic/cheat sheet from Zippi might be helpful for those looking to get out of auto mode and gaining more control over their cameras. While section 1 is much more for those shooting with film the rest is relevant for digital photography.
These Are the Darkroom Techniques Photoshop's Tools Are Based On