Here is another character Emily from Corpse Bride where button has used the blue and purple hues. Another notable aspect of this character is the shape of the eyebrows, Tim Burton does this a lot with his characters to create a distressed, sad face.
"With this hand I will lift your sorrows. Your cup will never be empty, for I will be your wine. With this candle, I will light your way into darkness. With this ring, I ask you to be mine." Corpse Bride