She does know from experience. He trained her in the Red Room. He doesn't remember her, and we've seen no evidence in the MCU that she remembers him from the Red Room, but these two DO know each other.

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Of course Peggy can lift can Steve and Bucky and Natasha...why is this a question? - visit to grab an unforgettable cool 3D Super Hero T-Shirt!

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Nat and Sam are like the sassiest Avengers. That's why they're the only ones who can keep up with Steve Rogers.

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So I like Bucky & Nat when they're like this. No romantic side story. Just two friends pranking their other friends. Ace.

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JAMES. NATALIA. STOP THAT RIGHT NOW.<<<*flips off of a building Matt Murdock style*

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Clint is all sulky about getting shot at and Natasha laughs and says that's just how Bucky makes friends, while Bucky tries to explain he didn't mean anything by it.

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